The comparative study of electrocatalytic activity of various anode materials in respect to the oxidation of nitroanilines

Zahorulko, S. and Shmychkova, O. and Luk’yanenko, T. and Dmitrikova, L. and Velichenko, A. (2019) The comparative study of electrocatalytic activity of various anode materials in respect to the oxidation of nitroanilines. Materials Today: Proceedings, 6. pp. 242-249. ISSN 2214-7853

[img]
Preview
Text
L. Dmitrokova.pdf

Download (780kB) | Preview
Official URL: http://www.materialstoday.com/proceedings

Abstract

The comparative study of electrocatalytic activity of DSA, lead dioxide and F-PbO2 has been performed. It has been shown that the processes of electrochemical oxidation of nitroanilines on investigated materials occur qualitatively the same and differ only in the rate. This suggests the invariability of the mechanism of their oxidation on different materials that allows one for a correct comparison of their electrocatalytic activity. The maximum interest for the electrochemical destruction of nitroanilines represents lead dioxide electrodes modified by fluorine to which a rate constant of p-nitroaniline oxidation increases in 3 times compared with nonmodified electrodes.

Item Type: Article
Uncontrolled Keywords: Lead dioxide; DSA; methanesulfonate electrolyte; oxygen evolution; electrooxidation of organic compounds
Subjects: Organic Chemistry
Divisions: Departments > Department of Biochemistry, Medical and Pharmaceutical Chemistry
Depositing User: Елена Шрамко
Date Deposited: 29 Oct 2019 11:46
Last Modified: 29 Oct 2019 11:46
URI: http://repo.dma.dp.ua/id/eprint/4424

Actions (login required)

View Item View Item